I used to use VLC for a lot of things but I got tired of it's wonky interface. I'm using Windows Media Player 11 to view everything now.
By the way, by default Windows Media Player cannot playback DVDs because Windows does not come with an DVD decoder installed. Typically you can solve this by just installing the software that comes with your DVD player, or by downloading something that includes one (like Nvidia PureView Decoder).
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