AH, you didn't pry it out, but it fell out... You may have a bad evap canister as well. I still say it is not the cause of the fueling issue, as the two systems (the evap system and the filler system) are separate and unconnected.
Looking at the picture of the water bottle with charcoal in it, if that's ALL that you got out of it, I wouldn't worry much about lowering it's capability to do it's job, but you may have issues down the road if it pukes up more.
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